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Highly excited Rydberg states and their interactions play an important role in quantum computing and simulation. These properties can be predicted accurately for alkali atoms with simple Rydberg level structures. However, an extension of these methods to more complex atoms such as alkaline-earth atoms has not been demonstrated or experimentally validated. Here, we present multichannel quantum defect models for highly excited ${}^{174}\mathrm{Yb}$and ${}^{171}\mathrm{Yb}$Rydberg states with $L\le 2$. The models are developed using a combination of existing literature data and new, high-precision laser and microwave spectroscopy in an atomic beam, and validated by detailed comparison with experimentally measured Stark shifts and magnetic moments. We then use these models to compute interaction potentials between two Yb atoms, and find excellent agreement with direct measurements in an optical tweezer array. From the computed interaction potential, we identify an anomalous Förster resonance that likely degraded the fidelity of previous entangling gates in ${}^{171}\mathrm{Yb}$using $F=3/2$Rydberg states. We then identify a more suitable $F=1/2$state, and achieve a state-of-the-art controlled- gate fidelity of $\mathcal{F}=0.994\left(1\right)$, with the remaining error fully explained by known sources. This work establishes a solid foundation for the continued development of quantum computing, simulation, and entanglement-enhanced metrology with Yb neutral atom arrays. Published by the American Physical Society2025 

The development of scalable, high-fidelity qubits is a key challenge in quantum information science. Neutral atom qubits have progressed rapidly in recent years, demonstrating programmable processors1,2 and quantum simulators with scaling to hundreds of atoms3,4. Exploring new atomic species, such as alkaline earth atoms5,6,7, or combining multiple species8 can provide new paths to improving coherence, control and scalability. For example, for eventual application in quantum error correction, it is advantageous to realize qubits with structured error models, such as biased Pauli errors9 or conversion of errors into detectable erasures10. Here we demonstrate a new neutral atom qubit using the nuclear spin of a long-lived metastable state in 171Yb. The long coherence time and fast excitation to the Rydberg state allow one- and two-qubit gates with fidelities of 0.9990(1) and 0.980(1), respectively. Importantly, a large fraction of all gate errors result in decays out of the qubit subspace to the ground state. By performing fast, mid-circuit detection of these errors, we convert them into erasure errors; during detection, the induced error probability on qubits remaining in the computational space is less than 10−5. This work establishes metastable 171Yb as a promising platform for realizing fault-tolerant quantum computing.